Just found out that turning off notification in 19.04 for a specific application can be achieved in Settings > Applications > <Srollling the left panel to the desired app and click on it (VLC-Player, in my case) > Notifications OFF.
This at least avoids the annoying pop-ups every 3 minutes.
On 18.10 added “X-GNOME-UsesNotifications=true” to the two printer apps in /usr/share/applications, then reboot. Turned off printers in the Notifications, no change Same thing on 19.04.
ok - on 19.04 - I opened Settings - then Applications - chose Printers - and turned off notifications. i.e. I ignored Settings - Notifications - …
I printed - no popup notifications was visible - raven notifications still recorded that a notification happened - so that sounds like good news to me.